Dichloridobis(3-chloropyridine-κN)zinc [ZnCl2(C5H4ClN)2]
2011
Crystal Structure of a Zinc Complex with 3-Chloropyridine
publication
Evidence: moderate
Author Information
Author(s): Liu Yan-Hui, Xu Lin, Dai Dong-Mei, Zou Jian-Wei
Primary Institution: Zhejiang University
Hypothesis
The study investigates the crystal structure of a zinc(II) complex coordinated by 3-chloropyridine ligands.
Conclusion
The crystal structure reveals discrete complexes where zinc(II) is coordinated by two 3-chloropyridine ligands and two chloride anions, forming slightly distorted tetrahedra.
Supporting Evidence
- The zinc(II) cation is coordinated by two chloride anions and two 3-chloropyridine ligands.
- The coordination environment around the zinc cations consists of slightly distorted tetrahedra.
- Intermolecular C—Cl···Cl—C interactions were observed in the crystal structure.
Takeaway
The researchers looked at how zinc atoms connect with certain molecules to form a specific structure, which is important for understanding how these materials work.
Methodology
Single crystal X-ray diffraction was used to characterize the crystal structure.
Digital Object Identifier (DOI)
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