catena-Poly[[[diaqua(1,3-benzimidazole-κN3)manganese(II)]-μ-benzene-1,3-dicarboxylato-κ3O1,O1′:O3] dihydrate]
2011
Study of a Manganese Complex with Benzimidazole and Benzene-Dicarboxylate
publication
Evidence: moderate
Author Information
Author(s): Wang Xiao-Hui
Primary Institution: Zhejiang College of Construction, Hangzhou, People's Republic of China
Conclusion
The study presents a polymeric manganese(II) complex that exhibits π–π stacking and extensive hydrogen bonding in its crystal structure.
Supporting Evidence
- The manganese(II) ion is coordinated by two benzenedicarboxylate anions, one benzimidazole ligand, and two water molecules.
- The crystal structure shows π–π stacking between nearly parallel benzimidazole aromatic ring systems.
- Extensive hydrogen bonding is present in the crystal structure.
Takeaway
Scientists created a special manganese compound that has some interesting stacking patterns between its parts, which could help in understanding how electrons move in nature.
Methodology
The compound was synthesized by mixing benzimidazole with manganese(II) acetate and benzenedicarboxylic acid in an ethanol solution, followed by refluxing and crystallization.
Digital Object Identifier (DOI)
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