[μ-Bis(diphenylphosphanyl)ethane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[tris(4-(methoxyphenyl)arsane-3κAs]-triangulo-triruthenium(0) chloroform monosolvate [Ru3(C21H21AsO3)(C26H24P2)(CO)9]·CHCl3
2011
Synthesis and Structure of a Triangulo-Triruthenium Compound
publication
Evidence: moderate
Author Information
Author(s): Shawkataly Omar bin, Khan Imthyaz Ahmed, Sirat Siti Syaida, Yeap Chin Sing, Fun Hoong-Kun
Primary Institution: Universiti Sains Malaysia
Hypothesis
The study investigates the synthesis and structural characteristics of a new triangulo-triruthenium compound.
Conclusion
The compound features a unique arrangement of ligands and carbonyl groups that stabilize its crystal structure.
Supporting Evidence
- The asymmetric unit consists of one molecule of the triangulo-triruthenium complex and one chloroform solvent molecule.
- The ligands are arranged in a way that stabilizes the structure through hydrogen bonds.
- The study contributes to the understanding of transition metal-carbonyl clusters.
Takeaway
Scientists made a new chemical compound with three ruthenium atoms and studied its structure to understand how it holds together.
Methodology
The compound was synthesized by refluxing equimolar quantities of precursors in a nitrogen atmosphere, and its structure was analyzed using X-ray crystallography.
Digital Object Identifier (DOI)
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