Dibromido[(1R,2R,N1S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ3N,N′,N′′]cadmium [CdBr2(C12H19N3)]
2011

Chiral Cadmium Complex with Bromide Ions

publication Evidence: moderate

Author Information

Author(s): Yin Run-Ting, Cao Zhe, Cheng Lin

Primary Institution: Southeast University

Conclusion

The study presents a new chiral cadmium complex that is enantiomerically pure and has a distorted square pyramidal coordination environment.

Supporting Evidence

  • The cadmium atom is coordinated by three nitrogen atoms and two bromide ions.
  • The complex is enantiomerically pure and corresponds to the S,R,R diastereoisomer.
  • The molecules form a one-dimensional hydrogen bonding network.

Takeaway

Scientists created a special cadmium compound that is chiral, meaning it has a unique shape that can be useful in making other materials or reactions work better.

Methodology

The compound was synthesized by mixing a chiral ligand with cadmium bromide in a methanol solution, followed by slow evaporation to obtain crystals.

Digital Object Identifier (DOI)

10.1107/S1600536811007033

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