N-[Bis(dimethyl­amino)­methyl­idene]-2-[(triphenyl­meth­yl)sulfan­yl]ethanaminium hexa­fluoro­phosphate
2011

Study of a New Organic Compound with Sulfur and Nitrogen

publication Evidence: moderate

Author Information

Author(s): Neuba Adam, Flörke Ulrich, Henkel Gerald

Primary Institution: Universität Paderborn

Hypothesis

The study investigates the molecular structure and properties of a new sulfur guanidine compound.

Conclusion

The synthesized compound exhibits a unique molecular structure with significant charge delocalization.

Supporting Evidence

  • The compound shows a protonated guanidyl group bridged by an ethylene linker.
  • Charge delocalization is observed over the three N—C bonds in the guanidinium unit.
  • The crystal structure reveals an N—H⋯F interaction between the cation and anion.

Takeaway

Scientists created a new chemical compound that has special properties because of how its atoms are arranged.

Methodology

The compound was synthesized and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811014929

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