[Malonato(2−)-κ2 O,O′]bis(1,10-phenanthroline-κ2 N,N′)zinc(II) pentahydrate [Zn(C3H2O4)(C12H8N2)2]·5H2O
2011
Zinc(II) Complex with 1,10-Phenanthroline
publication
Evidence: moderate
Author Information
Author(s): Chen Yan-Min, Xie Qing-Fan
Primary Institution: Quanzhou Normal University
Hypothesis
The study aims to synthesize and characterize a new zinc(II) complex with 1,10-phenanthroline as a co-ligand.
Conclusion
The synthesized zinc(II) complex exhibits a distorted octahedral geometry and is stabilized by hydrogen bonding and π-π interactions.
Supporting Evidence
- The zinc(II) cation is coordinated by four nitrogen atoms and two oxygen atoms.
- The crystal structure shows a three-dimensional network stabilized by hydrogen bonds and π-π interactions.
- Single crystals suitable for X-ray analysis were obtained through slow evaporation.
Takeaway
Scientists made a new zinc compound and found it has a special shape and sticks together with other molecules in a unique way.
Methodology
The complex was synthesized from 1,10-phenanthroline, zinc nitrate, and malonic acid, followed by characterization using single-crystal X-ray diffraction.
Digital Object Identifier (DOI)
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