1,4-Bis[(2-pyridylethyl)iminomethyl]benzene
2011
Study of a New Ligand Structure
publication
Evidence: moderate
Author Information
Author(s): Chiririwa Haleden, Moss John R., Su Hong, Hendricks Denver, Meijboom Reinout
Primary Institution: Department of Chemistry, University of Cape Town
Hypothesis
This work demonstrates the first example of a neutral pyridinyldimine-based bridging ligand.
Conclusion
The title compound exhibits a unique crystal structure stabilized by weak hydrogen bonds.
Supporting Evidence
- The compound crystallized in space group P21/n with Z = 2.
- The dihedral angle between the benzene and pyridine rings is 10.94°.
- Weak intermolecular hydrogen bonding and C—H⋯π interactions were observed.
Takeaway
The researchers created a new chemical compound that can help in binding metals, and they found that it has a special structure.
Methodology
The compound was synthesized by mixing benzene-1,4-dicarboxaldehyde with 2-(pyridin-2-yl)ethanamine in methanol and analyzed using X-ray structure analysis.
Digital Object Identifier (DOI)
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