N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) [V(C14H8BrClN2O2)(CH3O)O(CH4O)]
2011
New Oxovanadium Complex with Hydrazone Ligand
publication
Author Information
Author(s): Fu-Ming Wang
Primary Institution: Dezhou University
Conclusion
The study reports a new oxovanadium(V) complex with a hydrazone ligand that exhibits a distorted octahedral geometry.
Supporting Evidence
- The VV atom in the complex is six-coordinated, forming a distorted octahedral geometry.
- The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2°.
- Adjacent molecules in the crystal structure are linked through intermolecular hydrogen bonds.
Takeaway
Scientists created a new chemical compound using specific ingredients, and it has a unique shape that helps it bond with other molecules.
Methodology
The complex was synthesized by mixing 5-bromosalicylaldehyde, 2-chlorobenzohydrazide, and VO(acac)2 in methanol, followed by reflux and slow evaporation to form crystals.
Digital Object Identifier (DOI)
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