Structure and Behavior of Human α-Thrombin upon Ligand Recognition: Thermodynamic and Molecular Dynamics Studies
2011

Understanding Thrombin Structure and Stability through Ligand Binding

publication Evidence: moderate

Author Information

Author(s): Silva Vivian de Almeira, Cargnelutti Maria Thereza, Giesel Guilherme M., Palmieri Leonardo C., Monteiro Robson Q., Verli Hugo, Lima Luis Mauricio T. R.

Primary Institution: Federal University of Rio de Janeiro (UFRJ), Brazil

Hypothesis

How does ligand binding affect the conformation and stability of alpha-thrombin in solution?

Conclusion

Ligand binding to alpha-thrombin significantly alters its conformation and increases its stability against denaturation.

Supporting Evidence

  • Binding of PPACK to thrombin increases its thermal stability.
  • Molecular dynamics simulations show minimal structural changes upon ligand binding.
  • SAXS measurements indicate similar overall shapes for free and PPACK-bound thrombin.

Takeaway

When a special molecule binds to thrombin, it helps the protein stay stable and change shape, which is important for how it works in the body.

Methodology

The study used small-angle X-ray scattering, molecular dynamics simulations, and thermodynamic measurements to analyze thrombin's structure and stability.

Limitations

The study lacks high-resolution structures of ligand-free thrombin and relies on simulations and indirect measurements.

Digital Object Identifier (DOI)

10.1371/journal.pone.0024735

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