Bis(2-amino-4-methyl­pyridinium) bis­(pyridine-2,6-dicarboxyl­ato)cuprate(II)
2011

Study of a New Copper Complex with Pyridine-2,6-Dicarboxylic Acid

publication Evidence: moderate

Author Information

Author(s): Aghabozorg Hossein, Mofidi Rouchi Azadeh, Notash Behrouz, Mirzaei Masoud

Primary Institution: Islamic Azad University, North Tehran Branch

Hypothesis

The reaction between pyridine-2,6-dicarboxylic acid and 2-amino-4-methylpyridine with copper(II) nitrate will yield a new coordination compound.

Conclusion

The study successfully synthesized a new copper complex with a distorted octahedral geometry.

Supporting Evidence

  • The compound exhibits a distorted octahedral geometry around the CuII ion.
  • Intermolecular hydrogen bonds and π-π contacts stabilize the crystal structure.
  • The synthesis involved a reaction in methanol followed by crystallization.

Takeaway

Scientists mixed some chemicals to create a new type of crystal that has special shapes and properties.

Methodology

The compound was synthesized by mixing solutions of pyridine-2,6-dicarboxylic acid, 2-amino-4-methylpyridine, and copper(II) nitrate in methanol, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811001139

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