Diaquabis[5-(1-oxidopyridin-1-ium-2-yl)-1,2,3,4-tetrazolido]manganese(II) dihydrate [Mn(C6H4N5O)2(H2O)2]·2H2O
2011
Structure of a Manganese(II) Tetrazolate Complex
publication
Evidence: high
Author Information
Author(s): Gao Feng, Yao Chang-Sheng, Lu Zai-Sheng, Shi Yan-Hui
Primary Institution: Xuzhou Normal University
Hypothesis
The study aims to elucidate the structure of a novel substituted tetrazolato-metal complex.
Conclusion
The crystal structure reveals a manganese(II) ion coordinated in a distorted octahedral geometry by tetrazolate ligands and water molecules.
Supporting Evidence
- The manganese(II) ion is coordinated by two bidentate ligands and two water molecules.
- The structure features hydrogen bonds that create a three-dimensional network.
- The study provides insights into the coordination chemistry of tetrazolate complexes.
Takeaway
Scientists studied a special manganese compound to see how it is built. They found that it has a unique shape with certain connections between its parts.
Methodology
The compound was synthesized by mixing solutions of 5-(2-pyridyl-1-oxide)tetrazole and manganese(II) perchlorate, followed by crystallization and X-ray analysis.
Digital Object Identifier (DOI)
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