Metal-Organic Papers (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV) [Sn(C6H5)3(C11H14NS2)]
2011

Study of a Tin Compound with Dithiocarbamate Ligand

publication

Author Information

Author(s): Kamaludin Nurul Farahana, Baba Ibrahim, Awang Normah, Mohamed Tahir Mohamed Ibrahim, Tiekink Edward R. T.

Primary Institution: Universiti Kebangsaan Malaysia

Conclusion

The study reveals the molecular structure of a tin compound with a dithiocarbamate ligand, showing tetrahedral coordination and helical supramolecular chains.

Supporting Evidence

  • The compound features a tetrahedrally coordinated Sn atom.
  • The dithiocarbamate ligand coordinates in a monodentate fashion.
  • The crystal structure shows helical supramolecular chains along the b axis.

Takeaway

The researchers looked at a special tin compound and found that it has a unique shape and structure that connects in a spiral way.

Methodology

The compound was synthesized using an in situ method involving the addition of carbon disulfide to an ethanolic solution of N-butylphenylamine, followed by the addition of triphenyltin(IV) chloride.

Digital Object Identifier (DOI)

10.1107/S1600536811012426

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