Reactivity of an Iridium Methylidene Complex in Solid/Gas Conditions
Author Information
Author(s): Altus Kristof M., Sajjad M. Arif, Gyton Matthew R., Whitwood Adrian C., Page Samuel J., Macgregor Stuart A., Weller Andrew S.
Primary Institution: Department of Chemistry, University of York
Hypothesis
Can low-temperature solution synthesis and recrystallization be combined with subsequent room-temperature solid/gas reactivity to stabilize a solution-unstable organometallic complex?
Conclusion
The study demonstrates that a reactive organometallic methylidene complex can be stabilized in the crystalline phase and undergo solid/gas reactions.
Supporting Evidence
- The iridium methylidene complex was stabilized in the crystalline state.
- Solid/gas reactions were successfully performed with hydrogen, carbon monoxide, and ammonia.
- Periodic density functional theory confirmed the bond character of the iridium methylidene complex.
Takeaway
Scientists found a way to keep a special chemical stable so they could study how it reacts with gases, like hydrogen and ammonia.
Methodology
The study used low-temperature recrystallization and solid/gas reactions to explore the reactivity of an iridium methylidene complex.
Digital Object Identifier (DOI)
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