Tetra­kis(μ-4-tert-butyl­benzoato)-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ2O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)] [Nd2(C11H13O2)6(C11H14O2)2(H2O)2]
2011

New Neodymium Complex with 4-tert-butylbenzoic Acid

publication Evidence: moderate

Author Information

Author(s): Yang Juan, Dai Jun

Primary Institution: Henan Polytechnic University

Hypothesis

The study investigates the synthesis and crystal structure of a new neodymium complex formed with 4-tert-butylbenzoic acid.

Conclusion

The reaction produced a dinuclear neodymium complex with specific coordination and structural characteristics.

Supporting Evidence

  • The complex exhibits non-crystallographic Ci symmetry.
  • Each neodymium ion is coordinated by multiple ligands and water molecules.
  • The structure is stabilized by hydrogen bonds forming one-dimensional chains.

Takeaway

Scientists made a new compound using neodymium and a special acid, and they found out how it is structured.

Methodology

The complex was synthesized by reacting neodymium nitrate with 4-tert-butylbenzoic acid in an autoclave at high temperature.

Digital Object Identifier (DOI)

10.1107/S1600536811015194

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