Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate [Co(CN)2(C18H18N4)]PF6
2011
Dicyanido[tris(2-pyridylmethyl)amine]cobalt(III) hexafluoridophosphate
publication
Author Information
Author(s): Yu Fan, Li Bao
Primary Institution: Jianghan University and Huazhong University of Science and Technology
Hypothesis
The study aims to synthesize new complexes using octacyanotungsten(IV) anions as templates.
Conclusion
The cobalt(III) centers in the compound are coordinated by two cyanides and a tris(2-pyridylmethyl)amine ligand, exhibiting a rigid octahedral geometry.
Supporting Evidence
- The cobalt(III) centers are coordinated by two cyanides and a tris(2-pyridylmethyl)amine ligand.
- The compound exhibits a rigid octahedral geometry.
- The crystal packing is stabilized by hydrogen bonding interactions.
Takeaway
Scientists made a new compound using special chemicals, and it has a unique shape that helps it hold onto other atoms.
Methodology
The compound was synthesized by layering solutions of cobalt and other chemicals, leading to the formation of yellow crystals after half a year.
Digital Object Identifier (DOI)
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