Diaqua­bis­(5-carb­oxy-2-ethyl-1H-imidazole-5-carboxyl­ato-κ2N3,O4)zinc trihydrate [Zn(C7H7N2O4)2(H2O)2]·3H2O
2011

Zinc Complex with Imidazole Carboxylate Ligands

publication Evidence: moderate

Author Information

Author(s): Zhang Gang

Primary Institution: Henan University of Urban Construction

Hypothesis

Coordination polymers based on 2-ethyl-4,5-imidazoledicarboxylate have been rarely reported.

Conclusion

The study successfully synthesized a zinc complex with a unique crystal structure involving imidazole carboxylate ligands.

Supporting Evidence

  • The zinc ion is coordinated by two imidazole carboxylate ligands and two water molecules.
  • The crystal structure exhibits extensive hydrogen bonding.
  • The compound was obtained through a hydrothermal synthesis method.

Takeaway

Scientists made a special zinc compound using a specific type of acid and water, and it formed a unique structure.

Methodology

The compound was synthesized by reacting zinc nitrate with 2-ethyl-4,5-imidazoledicarboxylic acid in an aqueous solution under hydrothermal conditions.

Digital Object Identifier (DOI)

10.1107/S160053681101676X

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