Metal-Organic Papers [2-Amino-4,6-bis­(2-pyrid­yl)-1,3,5-tri­azine-κ3N4,N5,N6]dichloridocadmium(II) [CdCl2(C13H10N6)]
2011

Crystal Structure of a Cadmium(II) Complex with a Triazine Ligand

publication Evidence: moderate

Author Information

Author(s): Cao Man-Li, Shi Lei

Primary Institution: Guangdong University of Education

Hypothesis

The study investigates the coordination properties of the HABPT ligand in a cadmium(II) complex.

Conclusion

The cadmium(II) complex exhibits a five-coordinated structure with a tridentate ligand coordination mode.

Supporting Evidence

  • The ligand HABPT coordinates to the cadmium ion through three nitrogen atoms and two chloride ions.
  • The crystal structure shows hydrogen bonding interactions that contribute to the stability of the compound.
  • The study provides insights into the coordination chemistry of asymmetric ligands.

Takeaway

Scientists made a new compound using cadmium and a special molecule that can hold onto it in a specific way, forming a unique structure.

Methodology

The ligand was synthesized and then reacted with cadmium chloride in ethanol and water, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811012517

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