trans-Diaquabis(1H-imidazole-4-carboxylato-κ2N,O)nickel(II)
2011

New Nickel Complex with Imidazole-4-Carboxylic Acid

publication Evidence: moderate

Author Information

Author(s): Zheng Shengrun, Cai Songliang, Fan Jun, Zhang Weiguang

Primary Institution: South China Normal University

Hypothesis

The study investigates the synthesis and structure of a new nickel(II) complex using 1H-imidazole-4-carboxylic acid.

Conclusion

The nickel(II) complex exhibits a distorted octahedral geometry and forms a three-dimensional supramolecular network through hydrogen bonding.

Supporting Evidence

  • The nickel(II) ion is located on an inversion center.
  • The complex shows a distorted octahedral geometry.
  • Intermolecular hydrogen bonds link the complex molecules into layers.
  • The study contributes to the understanding of coordination polymers.

Takeaway

Scientists made a new nickel compound using a special acid, and it has a unique shape that helps it stick together with other molecules.

Methodology

The complex was synthesized through a solvothermal reaction and characterized using X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811018824

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