Metal-Organic Papers
2011

Synthesis and Structure of a New Bismuth Compound

publication Evidence: moderate

Author Information

Author(s): Kawahata Masatoshi, Yasuike Shuji, Kinebuchi Izumi, Yamaguchi Kentaro, Kurita Jyoji

Primary Institution: Tokushima Bunri University

Conclusion

The study presents the synthesis and structural analysis of a new bismuth compound, revealing its unique coordination geometry.

Supporting Evidence

  • The compound exhibits a distorted trigonal-pyramidal arrangement.
  • An intramolecular coordination between the bismuth and nitrogen atoms was observed.
  • The bond distances and angles indicate a hypervalent structure.

Takeaway

Scientists made a new chemical compound with bismuth and studied its shape and structure to understand how it works.

Methodology

The compound was synthesized using a reaction between N,N-dimethylbenzylamine and chlorobis(4-methylphenyl)bismuthane, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536810043655

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