Dicarbonyl(η5-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) [Fe(C5H5)(C8H9S)(CO)2]
2011
Iron(II) Complex with Sulfur-Linked Phenyl Ring
publication
Evidence: moderate
Author Information
Author(s): Mkhize Dennis S., Nyamori Vincent O., Bala Muhammad D.
Primary Institution: University of KwaZulu-Natal
Hypothesis
The presence of sulfur in the compound is believed to increase the yield and affect the morphology of products obtained.
Conclusion
The study characterizes a new iron(II) complex with a specific geometric arrangement that may be useful in catalysis.
Supporting Evidence
- The compound is characterized by a thioethyl-linked phenyl ring and a cyclopentadienyl moiety.
- The geometry of the complex is described as a three-legged piano stool distorted octahedral.
- The study contributes to the understanding of iron-based organometallics in catalysis.
Takeaway
Scientists created a new iron compound that could help make materials like carbon nanotubes. They think the sulfur in it helps make more of the product.
Methodology
The compound was synthesized using a reaction between cyclopentadienylirondicarbonyl dimer and 2-chloroethyl phenyl sulfide in dry tetrahydrofuran.
Digital Object Identifier (DOI)
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