Bis(η3-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II) [Ni(C15H24NSi)2]
2011

Study of a Nickel Complex with Azaallyl Ligands

publication Evidence: moderate

Author Information

Author(s): Hao Junsheng, Liu Haimei, Yuan Hai-Yan

Primary Institution: Shanxi University

Conclusion

The study presents a nickel complex with unique structural properties influenced by steric effects.

Supporting Evidence

  • The nickel complex is homoleptic and centrosymmetric.
  • The coordination around the nickel atom is square-planar.
  • The distances between nickel and the ligands are influenced by steric hindrance.

Takeaway

Scientists created a special nickel compound that has two unique parts attached to it, and they found that nearby structures affect its shape.

Methodology

The compound was synthesized using standard Schlenk techniques and characterized through X-ray crystallography.

Digital Object Identifier (DOI)

10.1107/S1600536811009469

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