catena-Poly[[(2,2′-bipyridine)manganese(II)]-μ3-4,4′-sulfonyldibenzoato] [Mn(C14H8O6S)(C10H8N2)]
2011
Crystal Structure of a Manganese Complex
publication
Evidence: moderate
Author Information
Author(s): Yan Shi-Wei, Zhang Guang-Ju, Chen Hai-Yan, Chang Suo-Cheng, Zhang Fu-Tian
Primary Institution: Southwest University, Chongqing, People’s Republic of China
Conclusion
The study presents the crystal structure of a manganese complex with a distorted octahedral geometry, stabilized by various interactions.
Supporting Evidence
- The manganese ion is coordinated by four oxygen atoms and two nitrogen atoms.
- The structure features polymeric chains with specific distances between manganese atoms.
- Weak hydrogen bonds and π–π interactions help stabilize the crystal structure.
Takeaway
Scientists looked at a manganese compound and found that it has a special shape that helps it stick together with other molecules.
Methodology
The compound was synthesized by mixing manganese acetate, sulfonyl-dibenzoic acid, and 2,2'-bipyridine in water, then heated in an autoclave.
Digital Object Identifier (DOI)
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