Poly[bis­(acetonitrile-κN)bis­[μ3-bis(tri­fluoro­methane­sulfonyl)­imido-κ4 O,O′:O′′:O′′′]dilithium] [Li2(C2F6NO4S2)2(C2H3N)2]
2011

Structure of a Lithium Compound with Acetonitrile

publication Evidence: high

Author Information

Author(s): Seo Daniel M., Boyle Paul D., Henderson Wesley A.

Primary Institution: North Carolina State University

Conclusion

The study presents the crystal structure of a lithium compound coordinated with acetonitrile and bis(trifluoromethanesulfonyl)imide anions.

Supporting Evidence

  • The compound contains three symmetry independent lithium cations.
  • Two lithium cations are coordinated by six oxygen atoms in a pseudo-octahedral geometry.
  • The third lithium cation is four-coordinated by two oxygen and two nitrogen atoms.

Takeaway

The researchers looked at how lithium ions are arranged in a specific compound, showing how they are connected to other atoms.

Methodology

The structure was determined using X-ray diffraction techniques.

Digital Object Identifier (DOI)

10.1107/S1600536811011561

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