cis-(Acetonitrile-κN)aqua­bis­(2,2′-bipyrimidine-κ2N1,N1′)manganese(II) cis-diaqua­bis­(2,2′-bipyrimidine-κ2N1,N1′)manganese(II) tetrakis(perchlorate) dihydrate [Mn(C2H3N)(C8H6N4)2(H2O)][Mn(C8H6N4)2(H2O)2](ClO4)4·2H2O
2011

Study of a manganese complex with bipyrimidine ligands

publication Evidence: moderate

Author Information

Author(s): Ha Kwang

Primary Institution: Chonnam National University

Conclusion

The study presents a new manganese complex with distinct coordination geometries and hydrogen bonding interactions.

Supporting Evidence

  • The compound contains two distinct manganese complexes with different coordination geometries.
  • The crystal structure shows hydrogen bonding interactions between the complex molecules and solvent.
  • The study provides insights into the geometric and electronic properties of manganese complexes.

Takeaway

Scientists created a new manganese compound that has special shapes and connections between its parts, which helps us understand how these materials work.

Methodology

The compound was synthesized from manganese(II) perchlorate and bipyrimidine in ethanol, followed by crystallization from acetonitrile.

Digital Object Identifier (DOI)

10.1107/S1600536811015388

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