Revisiting Mechanism of NaOH Dechlorination Treatments for Bronze Conservation in Quantitative Study
2024

NaOH Dechlorination Treatments for Bronze Conservation

publication Evidence: moderate

Author Information

Author(s): Yang Xin, Wu Wei, Chen Kunlong

Primary Institution: University of Science and Technology Beijing

Hypothesis

Can NaOH effectively dechlorinate bronze artifacts to prevent corrosion?

Conclusion

The NaOH desalinization method effectively converts CuCl to Cu2(OH)3Cl, leading to an expansion of the rust layer.

Supporting Evidence

  • The NaOH treatment converts CuCl into more stable products while achieving desalination.
  • Electrochemical treatments significantly enhance the conversion of CuCl.
  • Chloride ion concentration measurements indicate varying effectiveness based on solution concentration.

Takeaway

This study shows that using a special method with NaOH can help clean bronze artifacts by removing harmful chlorine.

Methodology

Samples were prepared using a powder pressing method and treated with NaOH solutions at varying concentrations and current densities to analyze dechlorination effectiveness.

Limitations

The study may not fully account for the complexities of real archaeological samples and their varied corrosion states.

Digital Object Identifier (DOI)

10.3390/ma17246126

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