Sodium piperidine-1-carbodithioate dihydrate
2011

Sodium piperidine-1-carbodithioate dihydrate

publication Evidence: moderate

Author Information

Author(s): Mafud Ana C., Gambardella Maria Teresa P.

Primary Institution: Instituto de Química de São Carlos, Universidade de São Paulo

Conclusion

The study presents the crystal structure of sodium piperidine-1-carbodithioate dihydrate, revealing its unique two-dimensional network and hydrogen bonding interactions.

Supporting Evidence

  • The crystal structure shows a sodium cation coordinated to sulfur and oxygen atoms.
  • The piperidine ring exhibits positional disorder with two occupancy factors.
  • Hydrogen bonds involving lattice water molecules stabilize the crystal structure.

Takeaway

This study looks at a special type of salt made from sodium and piperidine that forms a unique crystal structure with water molecules helping to hold it together.

Methodology

The compound was prepared by mixing piperidine, sodium hydroxide, and carbon disulfide in a cold ethanol/water solution, followed by crystallization.

Digital Object Identifier (DOI)

10.1107/S1600536811022604

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