固相萃取-高效液相色谱-三重四极杆质谱法分析饮用水处理厂水样中7种香豆素
2025

Analyzing Seven Coumarins in Drinking Water Using Advanced Techniques

publication Evidence: high

Author Information

Author(s): JIAO Wenmei, YANG Jingming, XU Ce, GAO Fukang, SHEN Luyao, YUAN Yubo, GUO Zhifen, HUANG Guang

Primary Institution: Jiangsu Second Normal University

Hypothesis

A method for analyzing coumarins in drinking water can be developed using solid-phase extraction and high-performance liquid chromatography coupled with mass spectrometry.

Conclusion

The developed method accurately monitors coumarins in drinking water and assesses the effectiveness of treatment processes.

Supporting Evidence

  • The method showed good linearity with correlation coefficients greater than 0.99.
  • Detection limits for the coumarins ranged from 0.67 to 1.12 ng/L.
  • Recoveries of the coumarins were between 61.4% and 91.5% at different spiked levels.
  • 7-hydroxycoumarin, 6,7-dihydroxycoumarin, and coumarin were detected in 100% of the samples analyzed.
  • Chlorinated coumarins were only detected in treated water, indicating their formation during disinfection.
  • The method is efficient and can be automated for routine monitoring.
  • Matrix effects were evaluated and found to be manageable with appropriate sample preparation.
  • The study highlights the importance of monitoring coumarins in drinking water for public health.

Takeaway

This study created a way to check for certain chemicals in drinking water that can be harmful, helping to keep our water safe.

Methodology

The study used solid-phase extraction followed by high-performance liquid chromatography and triple quadrupole mass spectrometry to analyze water samples.

Digital Object Identifier (DOI)

10.3724/SP.J.1123.2024.06014

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