Tris(4,4′-bi-1,3-thiazole-κ2N,N′)iron(II) tetrabromidoferrate(III) bromide [Fe(C6H4N2S2)3][FeBr4]Br
2011
Crystal Structure of a Metal-Organic Compound
publication
Evidence: moderate
Author Information
Author(s): Abedi Anita, Amani Vahid, Safari Nasser
Primary Institution: Islamic Azad University, North Tehran Branch
Conclusion
The study presents the synthesis and crystal structure of a new metal-organic compound involving iron and thiazole ligands.
Supporting Evidence
- The compound features a distorted octahedral geometry around the iron(II) atom.
- Intermolecular hydrogen bonds and Br···π interactions stabilize the crystal structure.
- The study provides detailed bond lengths and angles for the iron-thiazole complex.
Takeaway
Scientists made a new compound using iron and a special molecule called thiazole, and they figured out what it looks like.
Methodology
The compound was synthesized by mixing 4,4'-bi-1,3-thiazole with FeBr3 in methanol, followed by recrystallization.
Digital Object Identifier (DOI)
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