Triethyl­ammonium bis­{2-[(2-oxido-5-nitro­benzylidene)amino]­benzoato}ferrate(III) monohydrate
2011

New Iron(III) Complex with Nitro-Substituted Ligand

publication Evidence: moderate

Author Information

Author(s): Chygorin Eduard N., Petrusenko Svetlana R., Kokozay Volodymyr N., Smal Yuri O., Bon Volodymyr V.

Primary Institution: National Taras Shevchenko University

Hypothesis

The formation of a new iron(III) complex can be achieved through a specific reaction scheme involving various reagents.

Conclusion

The study successfully synthesized a new iron(III) complex with a specific ligand and characterized its crystal structure.

Supporting Evidence

  • The iron(III) ion is hexa­coordinated by four O atoms and two N atoms.
  • The crystal structure consists of triethylammonium cations and complex anions linked by hydrogen bonds.
  • The synthesis involves a reaction with Co, FeCl2, MnCl2, and a specific ligand.

Takeaway

Scientists made a new compound using iron and some special chemicals, and they looked at its structure to understand how it works.

Methodology

The compound was synthesized in air and characterized using X-ray crystallography.

Limitations

The compound is sparingly soluble in DMSO and DMF, which may limit its applications.

Digital Object Identifier (DOI)

10.1107/S1600536811011196

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