1-Chloromethyl-1,4-diazabicyclo[2.2.2]octane tetrachloridocuprate(II) (C7H15ClN2)[CuCl4]
2011

Study of a New Metal-Organic Compound

publication Evidence: low

Author Information

Author(s): Rong Tao

Primary Institution: Southeast University

Hypothesis

The title compound was studied as part of our work to obtain potential ferroelectric phase transition materials.

Conclusion

The compound has no dielectric anomalies in the temperature range 93–453 K, suggesting that it might be only a paraelectric.

Supporting Evidence

  • The organic dication is distorted, as indicated by the N—C—C—N torsion angles.
  • The [CuCl4]2- anion possesses typical Cu—Cl bonds.
  • The study contributes to the understanding of ferroelectric materials.

Takeaway

Scientists made a new compound and looked to see if it could be used in special materials that change when heated, but it didn't show the expected changes.

Methodology

The compound was synthesized by adding a solution of 1-(chloridomethyl)-1,4-diazabicyclo[2.2.2]octan-1-ium chloride to a solution of CuCl2 in water.

Limitations

The study did not find any dielectric anomalies in the tested temperature range.

Digital Object Identifier (DOI)

10.1107/S1600536811020782

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