Tuning the selectivity of NH3 oxidation via cooperative electronic interactions between platinum and copper sites
2024

Improving Ammonia Oxidation with a New Catalyst

publication 10 minutes Evidence: high

Author Information

Author(s): Lu Chen, Guan Xuze, Fei Zhaofu, Asakura Hiroyuki, Zhang Lun, Wang Zhipeng, Su Xinlian, Yao Zhangyi, Keenan Luke L., Hayama Shusaku, van Spronsen Matthijs A., Karagoz Burcu, Held Georg, Allen Christopher S., Hopkinson David G., Decarolis Donato, Callison June, Dyson Paul J., Wang Feng Ryan

Primary Institution: University College London

Hypothesis

Can a bi-metallic catalyst improve the selectivity and efficiency of ammonia oxidation to nitrogen?

Conclusion

The new bi-metallic catalyst achieves full ammonia conversion at a lower temperature while maintaining high nitrogen selectivity.

Supporting Evidence

  • The new catalyst achieves full NH3 conversion at 250°C, which is 50°C lower than commercial alternatives.
  • Operando studies show that the catalyst maintains high N2 selectivity across a wide temperature range.
  • The catalyst's performance is significantly better than that of standard commercial catalysts.

Takeaway

Scientists created a new catalyst that helps turn ammonia into nitrogen gas more efficiently and at lower temperatures, which is better for the environment.

Methodology

The catalyst was synthesized using galvanic replacement and evaluated in the NH3-SCO reaction under various conditions.

Limitations

The study may not account for all real-world conditions affecting catalyst performance.

Digital Object Identifier (DOI)

10.1038/s41467-024-54820-y

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