Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ3 O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate [Ca(C27H30N4O3)2](ClO4)2·2C2H3N
2011
Calcium Complex with H3saltren
publication
Evidence: high
Author Information
Author(s): Kose Muhammet, McKee Vickie
Primary Institution: Loughborough University
Hypothesis
This study investigates the crystal structure of a calcium complex with the ligand H3saltren.
Conclusion
The study successfully describes the crystal structure of a calcium complex with H3saltren, revealing its unique bonding and structural characteristics.
Supporting Evidence
- The calcium ion in the complex is six-coordinated.
- The study reports strong intramolecular hydrogen bonds.
- The cations are linked into chains via weak intermolecular interactions.
- Evidence of π-π stacking was observed in the crystal structure.
Takeaway
The researchers created a new compound by combining calcium with a special molecule, and they used X-ray techniques to see how the atoms are arranged.
Methodology
The compound was synthesized and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
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