trans-Bis(quinoline-8-amine-κ2N,N′)bis­(1,1,3,3-tetra­cyano-2-meth­oxy­propenido-κN)iron(II)
2024

New Iron(II) Complex with Quinoline-8-Amine

publication

Author Information

Author(s): Setifi Fatima, Setifi Zouaoui, Böhme Uwe, Al-Douh Mohammad Hadi, Satour Achouak

Primary Institution: Laboratoire de Chimie Ingénierie Moléculaire et Nanostructures (LCIMN) Université Ferhat Abbas Sétif 1

Conclusion

The synthesized iron(II) complex exhibits a distorted octahedral coordination geometry and shows potential for applications in spin-crossover materials.

Supporting Evidence

  • The iron(II) complex shows a distorted octahedral coordination geometry.
  • The coordination sphere includes bidentate quinoline-8-amine and tetra­cyano-2-meth­oxy­propenide anions.
  • The complex was synthesized using a solvothermal method.

Takeaway

Scientists made a new iron compound that can change its properties when conditions change, which could be useful for making new technology like sensors and displays.

Methodology

The compound was synthesized solvothermally from a mixture of iron(II) bis(tetra­fluorido­borate) hexa­hydrate, 8-amino­quinoline, and potassium 1,1,3,3-tetra­cyano-2-meth­oxy­propenide in water/ethanol.

Digital Object Identifier (DOI)

10.1107/S2414314624012197

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