First Insights into the Formation of Metal Soaps in Alkyd-Based Paints: A Proof-of-Concept Investigation Using FTIR Spectroscopy
2024

Formation of Metal Soaps in Alkyd-Based Paints

publication Evidence: moderate

Author Information

Author(s): Poli Tommaso, Haaf Michael P., Piccirillo Anna, Costa Abby P., Craig Rebecca L., Pozzi Federica

Primary Institution: Dipartimento di Chimica, Università di Torino

Hypothesis

Alkyd-based paints may undergo hydrolysis processes leading to the formation of metal soaps.

Conclusion

The study confirmed the formation of metal soaps in both mock-up and real alkyd-based paints.

Supporting Evidence

  • The study confirmed the formation of metal carboxylates in mock-up paints.
  • FTIR analysis showed the presence of metal soaps in both mock-up and contemporary artworks.
  • Different reactivity was observed for the materials based on the cations' availability.

Takeaway

This study looked at how certain paints can form metal soaps over time, which can affect their appearance and stability.

Methodology

The study involved preparing mock-up paints with an alkyd binder and analyzing them using FTIR spectroscopy.

Limitations

The study primarily focused on a limited number of pigments and mock-up paints, which may not represent all alkyd formulations.

Digital Object Identifier (DOI)

10.3390/molecules29245840

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