4-tert-Butyl-3′,4′-bis­(4-methyl­phen­yl)-3,4-dihydro-1H,4′H-spiro­[naphthalene-2,5′-[1,2]oxazol]-1-one
2011

Study of a New Organic Compound's Crystal Structure

publication Evidence: moderate

Author Information

Author(s): Akhazzane Mohamed, Zouihri Hafid, Bennani A., Kerbal Abdelali, Al Houari Ghali

Primary Institution: Université Sidi Mohammed Ben Abdellah, Fès, Morocco

Hypothesis

What is the crystal structure of the compound 4-tert-butyl-3′,4′-bis­(4-methyl­phen­yl)-3,4-dihydro-1H,4′H-spiro­[naphthalene-2,5′-[1,2]oxazol]-1-one?

Conclusion

The study reveals that the compound's crystal structure is stabilized by various hydrogen bonding interactions.

Supporting Evidence

  • The cyclohexanone ring adopts a half-chair conformation due to conjugation.
  • Dihedral angles between the naphthalene and methyl-benzene planes were measured.
  • Intermolecular hydrogen bonding interactions stabilize the crystal structure.

Takeaway

The researchers looked at a new chemical compound and found out how its atoms are arranged in a crystal, which helps us understand its properties.

Methodology

X-ray crystallography was used to determine the crystal structure of the compound.

Digital Object Identifier (DOI)

10.1107/S1600536811025086

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