cis-Dichloridotetrakis(trimethylphosphane-κP)ruthenium(II) benzene disolvate [RuCl2(C3H9P)4]·2C6H6
2011
Structure of a Ruthenium Complex
publication
Evidence: high
Author Information
Author(s): Fu Chen, Wen Ting Bin
Primary Institution: Xiamen University
Hypothesis
The study aims to report the structure of the cis-isomer of a ruthenium complex that has not been previously characterized.
Conclusion
The structure of the cis-[RuCl2(PMe3)4] complex was successfully determined, revealing a distorted octahedral geometry.
Supporting Evidence
- The complex exhibits a crystallographic mirror plane.
- The RuII atom adopts a distorted octahedral geometry.
- The study provides the first report of the cis-isomer of the ruthenium complex.
Takeaway
Scientists studied a special molecule made of ruthenium and found out how it is shaped and how its parts are arranged.
Methodology
The structure was determined using X-ray crystallography.
Digital Object Identifier (DOI)
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