Influence of ball milling parameters on the mechano-chemical conversion of polyolefins
2025

How Ball Milling Affects Plastic Recycling

publication Evidence: moderate

Author Information

Author(s): Adrian H. Hergesell, Claire L. Seitzinger, Justin Burg, Renate J. Baarslag, Ina Vollmer

Primary Institution: Utrecht University

Hypothesis

The study investigates how different ball milling parameters influence the mechano-chemical conversion of polyolefins into small hydrocarbons.

Conclusion

Using heavier grinding spheres and higher milling frequencies significantly increases the yield of small hydrocarbons from polypropylene.

Supporting Evidence

  • Heavier spheres produce more propene due to higher impact forces.
  • Higher milling frequencies lead to increased hydrocarbon yields.
  • Low plastic filling degrees enhance direct contact and chain cleavage.

Takeaway

This study shows that using heavy balls and shaking them fast helps break down plastic into useful chemicals better than other methods.

Methodology

The study used a Retsch shaker mill to depolymerize polypropylene and polyethylene by varying milling parameters such as sphere material, frequency, filling degree, and temperature.

Limitations

The study's findings may not be directly applicable to industrial settings due to the specific conditions used in the experiments.

Digital Object Identifier (DOI)

10.1039/d4mr00098f

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