Poly[tetra­aqua­bis­(μ3-benzene-1,3-di­carboxyl­ato-κ3 O:O′:O′′)bis­(μ2-benzene-1,3-dicarboxyl­ato-κ3 O,O′:O′′)[μ2-1,4-bis­(1,2,4-triazol-1-yl)butane-κ2 N:N′]tetra­zinc(II)] [Zn4(C8H4O4)4(C8H12N6)(H2O)4]
2011

Crystal Structure of a Zinc Coordination Polymer

publication Evidence: high

Author Information

Author(s): Fu Gui-Hong

Primary Institution: Liaohe Institute of Petroleum Technology, People’s Republic of China

Conclusion

The study presents the crystal structure of a zinc coordination polymer with specific coordination geometries.

Supporting Evidence

  • The crystal structure reveals a tetrahedral coordination of one zinc atom and a square-pyramidal coordination of another.
  • The zinc atoms are linked by benzene-1,3-dicarboxylate anions into layers.
  • Colorless block-shaped crystals suitable for X-ray analysis were obtained from a hydrothermal reaction.

Takeaway

Scientists looked at how zinc atoms are arranged in a special crystal, showing how they connect with other molecules.

Methodology

The crystal structure was determined using X-ray diffraction after synthesizing the compound through a hydrothermal reaction.

Digital Object Identifier (DOI)

10.1107/S1600536810051433

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