Oxonium picrate H3O+·C6H2N3O7−
2011

Crystal Structure of Oxonium Picrate

publication Evidence: moderate

Author Information

Author(s): Jin Shou-Wen, Chen Bing-Xia, Ge Yu-Shuang, Yin Hua-Bing, Fang Yu-Ping

Primary Institution: Tianmu College, ZheJiang A & F University, Lin’An, People’s Republic of China

Hypothesis

The study investigates the crystal structure of oxonium picrate formed from picric acid and 2-chloropyridine.

Conclusion

The crystal structure of oxonium picrate consists of a picrate anion and an oxonium cation, forming a two-dimensional sheet structure through hydrogen bonds.

Supporting Evidence

  • The oxonium cation is located on a crystallographic two-fold axis.
  • The picrate anions form stacks connected by π–π interactions.
  • Hydrogen bonds link the stacks to form a two-dimensional sheet structure.

Takeaway

Scientists looked at how a special chemical called oxonium picrate is built. They found that it forms layers that stick together like sheets of paper.

Methodology

The crystal was formed by recrystallization from a methanol solution and analyzed using X-ray diffraction.

Digital Object Identifier (DOI)

10.1107/S1600536811022574

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