Diamine Crosslinked Addition-Type Diblock Poly(Norbornene)s-Based Anion Exchange Membranes with High Conductivity and Stability for Fuel Cell Applications
2024

High-Performance Anion Exchange Membranes for Fuel Cells

publication Evidence: high

Author Information

Author(s): Li Quan, He Xiaohui, Feng Ling, Ye Jia, Zhang Wenjun, Huang Longming, Chen Defu

Primary Institution: Nanchang University

Hypothesis

Can diamine crosslinked addition-type diblock poly(norbornene)s-based anion exchange membranes achieve high conductivity and stability for fuel cell applications?

Conclusion

The developed membranes exhibited high hydroxide conductivity and excellent alkaline stability, making them promising candidates for fuel cell applications.

Supporting Evidence

  • The CL30-aPNB-TMHDA-TMA membrane exhibited the highest hydroxide conductivity of 138.84 mS cm−1 at 80 °C.
  • The membranes maintained 91.9% of their initial ion exchange capacity after 1008 hours in a 1 M NaOH solution.
  • The peak power density of the single cells assembled with the membranes was 266.2 mW cm−2.

Takeaway

Scientists made special membranes that help fuel cells work better by allowing electricity to flow easily and staying strong in tough conditions.

Methodology

The membranes were prepared using a combination of hydrophilic crosslinking and flexible alkoxy spacer chains, and their performance was evaluated through various tests.

Limitations

The performance may be affected by factors such as MEA preparation technology and testing environment.

Digital Object Identifier (DOI)

10.3390/polym16243534

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