Triphenyl[2-(triphenylphosphaniumyl)ethyl]phosphanium bis(periodate)
2011
New Phosphonium Salt Structure
publication
Evidence: moderate
Author Information
Author(s): Gholizadeh Mostafa, Mohammadi Zonoz Farrokhzad, Pourayoubi Mehrdad, Ebrahimpour Maliheh, Salehabadi Maryam
Primary Institution: Ferdowsi University of Mashhad
Hypothesis
What is the crystal structure of a new phosphonium salt?
Conclusion
The study successfully determined the crystal structure of a new phosphonium salt with specific geometric arrangements.
Supporting Evidence
- The phosphorus atoms in the dication are in a slightly distorted tetrahedral environment.
- The two P(C6H5)3 groups adopt a gauche conformation.
- Several C—H⋯O hydrogen bonds lead to a two-dimensional arrangement in the crystal.
Takeaway
Scientists created a new type of salt and looked at its structure. They found that the atoms are arranged in a special way.
Methodology
The salt was synthesized and its crystal structure was analyzed using X-ray diffraction.
Digital Object Identifier (DOI)
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