Metal-Organic Papers Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate [Pd(CH3)(C24H10F18NOP)(C2H3N)][SbF6]·0.5CH2Cl2
2011
Study of a Palladium Complex with a New Ligand
publication
Evidence: moderate
Author Information
Author(s): Li Liuzhong, White Peter S., Hao Aiyou
Primary Institution: Shandong University
Conclusion
The study presents a palladium complex with a distorted square-planar environment and highlights the presence of π–π interactions and weak intermolecular contacts.
Supporting Evidence
- The palladium atom is coordinated by an acetonitrile N atom and a methyl C atom.
- The crystal packing shows weak intermolecular C—H⋯F contacts.
- The ligand used in the study is a bidentate ligand with significant π–π interactions.
Takeaway
The researchers created a new palladium compound and found that its structure has some interesting interactions between its parts.
Methodology
The compound was synthesized and characterized using X-ray crystallography.
Digital Object Identifier (DOI)
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