Poly[dimethyl­ammonium [aquadi-μ2-oxalato-yttriate(III)] trihydrate]
2011

Synthesis and Structure of a Yttrium(III) Complex

publication Evidence: moderate

Author Information

Author(s): Lv Yao-Kang, Gan Li-Hua, Xu Liang, Zheng Hao-Wen, Liu Cao

Primary Institution: Tongji University

Hypothesis

The study investigates the synthesis and structural properties of a novel yttrium(III) complex.

Conclusion

The yttrium(III) complex exhibits a distorted tricapped trigonal-prismatic geometry and forms a three-dimensional network structure.

Supporting Evidence

  • The YIII atom is chelated by four oxalate ligands and one water molecule.
  • Each oxalate ligand bridges two YIII atoms, creating a three-dimensional network.
  • Various hydrogen-bonding interactions stabilize the crystal structure.

Takeaway

Scientists made a new compound using yttrium and oxalate, which forms a special structure that holds water and other molecules inside it.

Methodology

The compound was synthesized by mixing D-saccharic acid potassium salt, Y(NO3)3.6H2O, and N,N-dimethylformamide, followed by heating and slow evaporation.

Digital Object Identifier (DOI)

10.1107/S1600536811019209

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