A new MoVI Schiff base complex: methanol[N′-(3-methoxy-2-oxidobenzylidene)benzohydrazidato]dioxidomolybdenum(VI) [Mo(C15H12N2O3)O2(CH4O)]
2011
New Molybdenum Complex with Schiff Base Ligand
publication
Evidence: moderate
Author Information
Author(s): Sheikhshoaie Iran, Langer Vratislav, Yasrebi Seyed Ali
Primary Institution: Shahid Bahonar University, Kerman, Iran
Conclusion
The study presents the crystal structure of a new dioxomolybdenum(VI) complex with a Schiff base ligand, revealing its unique bonding and structural characteristics.
Supporting Evidence
- The MoVI ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate Schiff base ligand.
- Strong O—H⋯N hydrogen bonds form a C(5) chain around a 21 screw axis.
- The complex exhibits a distorted octahedral configuration.
Takeaway
Scientists created a new metal complex using molybdenum and a special type of chemical called a Schiff base, and they looked at its structure to understand how it works.
Methodology
The complex was synthesized by mixing MoO2(acac)2 with the ligand in a 1:1 molar ratio using dry methanol as a solvent, followed by refluxing.
Digital Object Identifier (DOI)
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