Metal-Organic Papers Bis[2-(4-hydroxyphenyl)acetato-κO]bis(1,10-phenanthroline-κ2N,N′)cadmium pentahydrate [Cd(C8H7O3)2(C12H8N2)2]·5H2O
2011
Crystal Structure of a Cadmium(II) Complex
publication
Evidence: moderate
Author Information
Author(s): Yu Yu-Ye
Primary Institution: Jinhua College of Vocation and Technology, Jinhua, Zhejiang, People’s Republic of China
Hypothesis
The study investigates the crystal structure of a new cadmium(II) complex with p-hydroxyphenylacetic acid and 1,10-phenanthroline.
Conclusion
The cadmium(II) complex exhibits a distorted trigonal-prismatic geometry with significant hydrogen bonding interactions.
Supporting Evidence
- The cadmium(II) ion is coordinated by two carboxylate O atoms and four N atoms from two chelating ligands.
- The structure is stabilized by O—H⋯O hydrogen bonds and π⋯π interactions.
- The compound was formed through a series of chemical reactions and crystallization steps.
Takeaway
Scientists created a new compound using cadmium and studied its structure. They found it has a unique shape and bonds that help hold it together.
Methodology
The compound was synthesized using cadmium hydroxide, p-hydroxyphenylacetic acid, and 1,10-phenanthroline in ethanol, followed by crystallization.
Digital Object Identifier (DOI)
Want to read the original?
Access the complete publication on the publisher's website