Dissolution Thermodynamics of the Solubility of Sulfamethazine in (Acetonitrile + 1-Propanol) Mixtures
2024

Solubility of Sulfamethazine in Acetonitrile and 1-Propanol Mixtures

publication Evidence: moderate

Author Information

Author(s): Delgado Daniel Ricardo, Castro-Camacho Jennifer Katiusca, Ortiz Claudia Patricia, Caviedes-Rubio Diego Ivan, Martinez Fleming

Primary Institution: Universidad Cooperativa de Colombia

Hypothesis

The study aims to evaluate the solubility of sulfamethazine in acetonitrile + 1-propanol cosolvent mixtures at various temperatures.

Conclusion

The solubility of sulfamethazine increases with temperature and is influenced by the acid/base character of the cosolvent mixtures.

Supporting Evidence

  • The solubility of sulfamethazine increases from pure 1-propanol to pure acetonitrile.
  • The dissolution process is endothermic and favored by the solution entropy.
  • The study shows a strong entropic compensation in the dissolution process.

Takeaway

This study looks at how well a medicine called sulfamethazine dissolves in two liquids mixed together, and it finds that it dissolves better when it's warmer.

Methodology

The solubility was determined using the shaking flask method and quantified by UV/Vis spectrophotometry.

Statistical Information

Statistical Significance

p<0.05

Digital Object Identifier (DOI)

10.3390/ph17121594

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