[1,2-Bis(diisopropylphosphanyl)ethane-κ2 P,P′]dichloridonickel(II)–9H-carbazole (1/2) [NiCl2(C14H32P2)]·2C12H9N
2011
Study of a Nickel Complex with Carbazole
publication
Evidence: moderate
Author Information
Author(s): Cañavera-Buelvas Farah, Flores-Alamo Marcos, García Juventino J.
Primary Institution: Facultad de Química, Universidad Nacional Autónoma de México
Conclusion
The nickel complex exhibits slight tetrahedral distortion from ideal square-planar geometry and shows potential for use in catalytic systems.
Supporting Evidence
- The nickel complex shows slight tetrahedral distortion from ideal square-planar geometry.
- Two symmetry-related 9H-carbazole molecules are present between adjacent nickel complexes.
- The synthesis involves heating a mixture of nickel and carbazole in THF.
Takeaway
The researchers created a nickel compound that can help in making catalysts, which are substances that speed up chemical reactions.
Methodology
The compound was synthesized from a THF solution of [Ni(dppe)H]2 and 9H-carbazole, followed by crystallization from dichloromethane.
Digital Object Identifier (DOI)
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