Structure of Apo- and Monometalated Forms of NDM-1—A Highly Potent Carbapenem-Hydrolyzing Metallo-β-Lactamase
2011

Structure of NDM-1: A Potent Carbapenem-Hydrolyzing Enzyme

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Author Information

Author(s): Kim Youngchang, Tesar Christine, Mire Joseph, Jedrzejczak Robert, Binkowski Andrew, Babnigg Gyorgy, Sacchettini James, Joachimiak Andrzej

Primary Institution: Midwest Center for Structural Genomics and Structural Biology Center, Argonne National Laboratory

Hypothesis

The study investigates the structural characteristics of NDM-1 to understand its mechanism of action and potential for inhibitor design.

Conclusion

The crystal structures of NDM-1 reveal an enlarged and flexible active site that allows for the hydrolysis of a wide range of β-lactam antibiotics.

Supporting Evidence

  • NDM-1 is capable of hydrolyzing a wide range of β-lactams, including carbapenems.
  • The crystal structures reveal an open and flexible active site.
  • Five loops contribute to the active site, enhancing substrate accommodation.
  • NDM-1 shows significant structural diversity compared to other metallo-β-lactamases.
  • Zinc ions play a crucial role in the enzyme's catalytic activity.

Takeaway

NDM-1 is an enzyme that helps bacteria resist antibiotics, and understanding its structure can help scientists design better drugs to fight these infections.

Methodology

The study involved crystallizing NDM-1 in different forms and analyzing its structure using X-ray diffraction.

Limitations

The study does not address the clinical implications of NDM-1's resistance mechanisms in detail.

Digital Object Identifier (DOI)

10.1371/journal.pone.0024621

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