Bis(2-amino-1,3-benzothia­zol-3-ium) tetra­chloridozincate(II) (C7H7N2S)2[ZnCl4]
2011

Crystal Structure of a Zinc Complex

publication Evidence: moderate

Author Information

Author(s): Kefi Riadh, Jeanneau Erwann, Lefebvre Frédéric, Ben Nasr Cherif

Primary Institution: Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte

Hypothesis

The study investigates the crystal structure of the compound (C7H7N2S)2[ZnCl4].

Conclusion

The compound exhibits a three-dimensional network held together by hydrogen bonds and coulombic attraction.

Supporting Evidence

  • The crystal structure shows a network of cations and anions.
  • Hydrogen bonds and π–π stacking interactions contribute to the stability of the structure.
  • The [ZnCl4]2− anion has a distorted tetrahedral geometry.

Takeaway

Scientists studied a special compound made of zinc and organic materials, and they found that it has a unique structure that holds everything together tightly.

Methodology

The compound was synthesized by evaporating a mixture of 2-aminobenzothiazole, zinc chloride, and HCl, resulting in colorless single crystals.

Digital Object Identifier (DOI)

10.1107/S1600536811015753

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