Metal-Organic Papers
2011

Zinc Complex with Hydroxybiphenyl Carboxylate Ligands

publication Evidence: moderate

Author Information

Author(s): Wu Wei-Ping, Wang Jun, Lu Lu, He Xi-Yang, Zou Li-Ke

Primary Institution: Sichuan University of Science and Engineering

Hypothesis

The study investigates the self-assembly of ZnII ions with specific organic ligands to form a new compound.

Conclusion

The compound features a distorted tetrahedral coordination of ZnII and forms a one-dimensional chain through hydrogen bonds.

Supporting Evidence

  • The ZnII atom is located on a twofold rotation axis.
  • The compound exhibits a distorted tetrahedral coordination.
  • The molecules are linked by O—H⋯O hydrogen bonds.

Takeaway

The researchers created a new zinc compound using special organic molecules, which stick together in a chain-like structure.

Methodology

The compound was synthesized by mixing zinc acetate, hydroxybiphenyl-4-carboxylic acid, phenanthroline, and sodium hydroxide in a solvent and heating it under pressure.

Digital Object Identifier (DOI)

10.1107/S1600536811012244

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